Solution Structures of Hauser Base iPr2NMgCl and Turbo-Hauser Base iPr2NMgCl·LiCl in THF and the Influence of LiCl on the Schle

ThesolutionstructuresofHauserbaseiPr2NMgClandTurbo-HauserbaseiPr2NMgCl·LiClinTHFhavebeenextensivelystudiedtounderstandtheirreactivityandbehaviorinorganicsynthesis.ThepresenceofLiClintheTurbo-HauserbasesignificantlyinfluencestheSchlenkequilibrium,alteringtheaggregationstateandenhancingthenucleophilicityofthemagnesiumspecies.Thismodificationleadstoimprovedperformanceindeprotonationandmetalationreactions,makingtheTurbo-HauserbaseamoreefficientreagentcomparedtothetraditionalHauserbase.Thestructuralinsightsgainedfromthesestudiesprovidevaluableinformationforoptimizingreactionconditionsanddesigningnewsyntheticmethodologies.